Day 1:
**Morning: Acropolis and Parthenon**
- Start your trip by exploring the Acropolis and marveling at the iconic Parthenon.
- Visit the Acropolis Museum to delve into the history of the ancient site.
**Afternoon: Plaka District**
- Stroll through the charming Plaka neighborhood.
- Have lunch in a traditional Greek taverna.
**Evening: Monastiraki Square**
- Explore Monastiraki Square and its vibrant flea market.
- Enjoy dinner in one of the local restaurants.
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Day 2:
**Morning: National Archaeological Museum**
- Spend the morning at the National Archaeological Museum.
- Explore its vast collection of ancient artifacts.
**Afternoon: Lycabettus Hill**
- Hike or take the funicular to the top of Lycabettus Hill for panoramic views.
- Have lunch at the hilltop restaurant.
**Evening: Kolonaki District**
- Explore the upscale Kolonaki district for shopping and dining.
- Enjoy dinner at a trendy restaurant.
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Day 3:
**Morning: Ancient Agora**
- Visit the Ancient Agora and Temple of Hephaestus.
- Explore the Stoa of Attalos and other historical structures.
**Afternoon: Kerameikos Archaeological Site**
- Discover the Kerameikos Cemetery and Archaeological Site.
- Have lunch at a nearby taverna.
**Evening: Thissio**
- Enjoy an evening walk in the Thissio neighborhood.
- Choose a restaurant with a view of the illuminated Acropolis.
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Day 4:
**Morning: National Garden of Athens**
- Relax in the National Garden of Athens.
- Visit the Zappeion Hall and the Panathenaic Stadium.
**Afternoon: Syntagma Square**
- Explore Syntagma Square and watch the changing of the guard at the Parliament.
- Have lunch at a cafe with a view of the square.
**Evening: Psiri District**
- Experience the nightlife in the Psiri district.
- Enjoy dinner and live music at a traditional Greek taverna.
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Day 5:
**Morning: Cape Sounion Day Trip**
- Take a day trip to Cape Sounion.
- Visit the Temple of Poseidon and enjoy the stunning coastal views.
**Afternoon: Beach Time or Vouliagmeni Lake**
- Relax at a beach like Vouliagmeni or enjoy the natural spa at Lake Vouliagmeni.
- Have a leisurely lunch by the water.
**Evening: Farewell Dinner**
- Return to Athens for a farewell dinner, perhaps in the scenic neighborhood of Anafiotika.
This itinerary offers a mix of ancient history, vibrant neighborhoods, and scenic spots. Adjust based on your interests and pace.